2026-08-03T16:27:45Z https://researchdata.tuwien.ac.at/oai2d

oai:researchdata.tuwien.ac.at:05hsk-05x05 2026-07-30T13:34:52Z community-mc openaire_data

4.3 TUW.TUDATA 10.48436/05hsk-05x05 oai:researchdata.tuwien.ac.at:05hsk-05x05 Ehrmann, Katharina Katharina Ehrmann 0000-0002-0161-0527 TU Wien Musil, Vojtech Vojtech Musil 0009-0007-9126-6785 TU Wien TU Wien 2026 macro-photoinitiator hyperbranached polyethylene vat photopolymerization Chemical sciences 3D printing migration Musil, Vojtech Vojtech Musil 0009-0007-9126-6785 TU Wien Uřičář, Jonáš Jonáš Uřičář Department of Electrotechnology, Faculty of Electrical Engineering, Czech Technical University in Prague, Technická 1902/2, 166 27, Prague, Czech Republic Ehrmann, Katharina Katharina Ehrmann 0000-0002-0161-0527 TU Wien 2026-06-17 2026-06-25 2026-07-30 eng 10.48436/4r536-gkv59 https://researchdata.tuwien.ac.at/communities/mc/ Creative Commons Attribution 4.0 International Context and methodology This dataset was created from original work conducted in the framework of a PhD project at University of Chemistry and Technology Prague and a CEEPUS-Exchange to TU Wien, and compiled in a publication. It provides the raw data of results presented and discussed therein.    Technical details In the following, description of the uploaded data is available. Detailed experimental procedures to arrive at the materials is included in the corresponding publication but abbreviations of formulations and materials used in the files are also described below. Folder "NMR spectra" Contains 1H, 13C and HSQC NMR spectra of the compounds UnBP and UnIC and 1H NMR spectra of compounds PE-BP1, PE-BP2, PE-BP3, PE-BP4, PE-IC1, PE-IC2, PE-IC3 and PE-IC4. NMR files require the software MestreNova or TopSpin to open, which are community standard softwares for this data type. Excel File "Figure Data" The file tabs are named according to the corresponding figure displaying the data in the manuscript and the data type displayed: Tab 1: Figure 2 UV-Vis spectrum Tab 2: Figure 4a Photo-dynamic scanning calorimetry (Photo-DSC) Tab 3: Figure 4b PhotoDSC Tab 4: Figure 5 Dynamic mechanical thermal analysis (DMTA) IBA series Tab 5: Figure 5 DMTA MIX series Tab 6: Figure 5 DMTA TDD series Tab 7: Figure 6 Tensile testing curves IBA series Tab 8: Figure 6 Tensile testing curves MIX series Tab 9: Figure 6 Tensile testing curves TDD series Folder "GPC" Size exclusion chromatography (SEC; gel permeation chromatography, GPC) data for the (functionalized) hyperbranched polyethylene macromonomers. Data is given in Malvern™ native formats including calibration files. To open the files, the Malvern™ software OmniSEC is required. Additionally, PDF reports are included for each of the samples. Folder “GCMS” Gas chromatography with mass spectrometric detector data for the leeching tests of prepared materials. Data is given in “.raw” format and can be opened by the softwares MestreNova or OpenChrom, which are community standard softwares for this data type. Abbreviations PE: PolyethyleneIC: Irgacure 2959, a common Type I photoinitiatorBP: benzophenone, a common Type II photoinitiatorUnIC: 10-undecenoate -based comonomer used to introduce Irgacure 2959 moieties to the hyperbranched polyethylene macrophotoinitiatorsUnBP: 10-undecenoate -based comonomer used to introduce benzophenone moieties to the hyperbranched polyethylene macrophotoinitiatorsIBA: isobornyl acrylate (CAS: 5888-33-5)TDD: tricyclodecanedimethanol diacrylate (CAS: 42594-17-2)MIX: equimolar mixture of IBA and TDD Formulations and Materials utilize the same abbreviations, according to their composition described next to the abbreviations. FWF Austrian Science Fund 013tf3c58 10.55776/RIC9773224 Orthogonal synthesis strategies for vat photopolymerization Czech Science Foundation 01pv73b02 GF22-09470L